储层矿物类型对致密油藏CO2驱替效果的影响Influence of reservoir mineral types on CO2 displacement effect of tight reservoir
吕利刚,张涛,李杰,孙建伟,郑海亮,王刚
Lü Ligang,ZHANG Tao,LI Jie,SUN Jianwei,ZHENG Hailiang,WANG Gang
摘要(Abstract):
为明确致密砂岩储层中石英、伊利石和绿泥石对CO_2驱油效率及孔隙动用特征的影响,分别选取以石英、伊利石、绿泥石为主要矿物类型的3种岩心,开展核磁共振扫描分析下的CO_2驱替实验,定量评价每种类型岩心在不同CO_2注入压力下小孔隙、大孔隙的原油采出程度,并分析了产出水中离子质量浓度变化。结果表明:目标储层以石英型和黏土矿物型为主,其中黏土矿物以伊利石和绿泥石为主;石英型岩心的CO_2驱替过程中,当CO_2注入压力小于等于最小混相压力时,大孔隙的原油动用程度大于小孔隙,当CO_2注入压力大于最小混相压力时,小孔隙的原油动用程度增加,而大孔隙的原油动用程度下降;伊利石型岩心大、小孔隙的原油采出程度最大,驱油效果最好,绿泥石型岩心大孔隙的原油采出程度很高,小孔隙的原油采出程度非常低,整体驱油效果最差;随着CO_2注入压力的增加,石英型岩心产出水中金属离子质量浓度大幅增加,伊利石型、绿泥石型岩心溶蚀后的钙、镁等离子产生沉淀,且绿泥石型岩心沉淀量最大,最易堵塞小孔隙。研究成果为致密砂岩油藏CO_2驱提供了参考和依据。
In order to clarify the impact of quartz, illite and chlorite in tight sandstone reservoir on CO_2 displacement efficiency and pores producing characteristics, 3 types of cores containing mainly quartz, illite and chlorite are used in CO_2 displacement experiment with NMR scanning analysis to quantitatively evaluate recovery degree of oil in small and large pores of each type of core under different CO_2 injection pressure and analyze mass concentration change of ions in produced water.The results show that the target reservoir is mainly quartz type and clay mineral type, and clay minerals are mainly illite and chlorite. In the process of CO_2 displacement of quartz-type core, oil in large pores has higher producing degree of oil than that in small pores when CO_2 injection pressure is lower than minimum miscible pressure and producing degree of oil in small pores increases when CO_2 injection pressure is higher than minimum miscible pressure. Illite-type core has the highest recovery degree of oil in large and small pores and optimum displacement effect. Chlorite-type core has high recovery degree of oil in large pores and low recovery degree of oil in small pores, with the poorest overall displacement effect.With the increase of CO_2 injection pressure, mass concentration of metal ions in produced water of quartz-type core increases greatly, dissolved calcium and magnesium ions in illite and chlorite type cores precipitate, and chlorite-type core has the largest precipitation amount and may block small pores.The research provides reference and basis for CO_2 flooding in tight sandstone reservoir.
关键词(KeyWords):
致密油藏;CO_2驱替;矿物;孔喉结构;核磁共振;注入压力
tight reservoir;CO_2 displacement;mineral;pore throat structure;nuclear magnetic resonance(NMR);injection pressure
基金项目(Foundation): 国家科技重大专项“鄂尔多斯盆地大型低渗透岩性地层油气藏开发示范工程”(2016ZX05050)
作者(Author):
吕利刚,张涛,李杰,孙建伟,郑海亮,王刚
Lü Ligang,ZHANG Tao,LI Jie,SUN Jianwei,ZHENG Hailiang,WANG Gang
参考文献(References):
- [1]李忠兴,屈雪峰,刘万涛,等.鄂尔多斯盆地长7段致密油合理开发方式探讨[J].石油勘探与开发,2015,42(2):217-225.LI Zhongxing, QU Xuefeng, LIU Wantao, et al. Development modes of Triassic Yanchang Formation Chang 7 Member tight oil in Ordos Basin, NW China[J]. Petroleum Exploration and Development,2015,42(2):217-225.
- [2]王建海,李娣,曾文广,等.塔河缝洞型油藏氮气+二氧化碳吞吐先导试验[J].大庆石油地质与开发,2015,34(6):110-117.WANG Jianhai,LI Di,ZENG Wenguang,et al. Pilot test of N2and CO2 huff and puff in Tahe fractured-vuggy reservoirs[J].Petroleum Geology&Oilfield Development in Daqing,2015,34(6):110-117.
- [3]黄小亮,贾新锋,周翔,等.延长油田低渗透油藏长岩心二氧化碳吞吐参数优化[J].新疆石油地质,2015,36(3):313-316.HUANG Xiaoliang,JIA Xinfeng,ZHOU Xiang,et al.Optimization of long core CO2 huff and puff experimental parameters in low permeability reservoir, Yanchang Oilfield[J]. Xinjiang Petroleum Geology,2015,36(3):313-316.
- [4]李晓骁,任晓娟,罗向荣.低渗透致密砂岩储层孔隙结构对渗吸特征的影响[J].油气地质与采收率,2018,25(4):119-124.LI Xiaoxiao,REN Xiaojuan,LUO Xiangrong. Influence of pore structures on the characteristic of spontaneous imbibition in lowpermeability tight sandstone reservoir[J]. Petroleum Geology and Recovery Efficiency,2018,25(4):119-124.
- [5] BOUZGARROU S, JEDLI H, STITI N, et al. Experimental adsorption and modelisation of CO2 on adsorbents collected from elborma field in South Tunisia[J]. Journal of Surface Engineered Materials and Advanced Technology, 2014, 5(1):52-60.
- [6] ELIEBID M, MAHMOUD M, ELKATATNY S, et al. Adsorption role in shale gas recovery and the feasibility of CO2 in shale enhanced gas recovery:A study on shale gas from Saudi Arabia[C]. Kuwait:SPE Kuwait Oil&Gas Show and Conference,2017.
- [7]孙会珠,朱玉双,魏勇,等.CO2驱酸化溶蚀作用对原油采收率的影响机理[J].岩性油气藏,2020,32(4):136-142.SUN Huizhu, ZHU Yushuang, WEI Yong, et al. Influence mechanism of acidification on oil recovery during CO2 flooding[J].Lithologic Reservoirs,2020,32(4):136-142.
- [8]胡伟,吕成远,王锐,等.水驱转CO2混相驱渗流机理及传质特征[J].石油学报,2018,39(2):201-209.HU Wei,LüChengyuan,WANG Rui,et al. Porous flow mechanism and mass transfer characteristics of CO2 miscible flooding after waterflooding[J].Acta Petrolei Sinica, 2018, 39(2):201-209.
- [9]肖娜,李实,林梅钦.CO2-水-岩石相互作用对岩石孔渗参数及孔隙结构的影响:以延长油田35-3井储层为例[J].油田化学,2018,35(1):85-90.XIAO Na,LI Shi,LIN Meiqin. Effect of CO2-water-rock interaction on porosity, permeability and pore structure characters of reservoir rock:A case study of 35-3 well in Yanchang Oilfield[J]. Oilfield Chemistry,2018,35(1):85-90.
- [10] LU Y Y,CHEN X Y,TANG J T,et al. Relationship between pore structure and mechanical properties of shale on supercritical carbon dioxide saturation[J].Energy,2019,172:270-285.
- [11] YIN H,ZHOU J P,XIAO X F,et al.Experimental study of the effects of sub-and super-critical CO2 saturation on the mechanical characteristics of organic-rich shales[J].Energy,2017,132:84-95.
- [12] PAN Y,HUI D,LUO P,et al.Experimental investigation of the geochemical interactions between supercritical CO2 and shale:Implications for CO2 storage in gas-bearing shale formations[J].Energy&Fuels,2018,32:1963-1978.
- [13]代全齐,罗群,张晨,等.基于核磁共振新参数的致密油砂岩储层孔隙结构特征:以鄂尔多斯盆地延长组7段为例[J].石油学报,2016,37(7):887-897.DAI Quanqi, LUO Qun, ZHANG Chen, et al. Pore structure characteristics of tight-oil sandstone reservoir based on a new parameter measured by NMR experiment:A case study of seventh Member in Yanchang Formation,Ordos Basin[J].Acta Petrolei Sinica,2016,37(7):887-897.
- [14]国家能源局.岩样核磁共振参数实验室测量规范:SY/T6490—2014[S].北京:石油工业出版社,2015.National energy administration. Specification for measurement of rock NMR parameter in laboratory:SY/T 6490—2014[S].Beijing:Petroleum Industry Press,2015.
- [15]郎东江,伦增珉,吕成远,等.页岩油注二氧化碳提高采收率影响因素核磁共振实验[J].石油勘探与开发,2021,48(3):1-10.LANG Dongjiang,LUN Zengmin,LüChengyuan,et al.Nuclear magnetic resonance experimental study of CO2 injection to enhanced shale oil recovery[J]. Petroleum Exploration and Development,2021,48(3):1-10.
- [16] AKBARABADI M,SARAJI S,PIRI M,et al.Nano-scale experimental investigation of in-situ wettability and spontaneous imbibition in ultratight reservoir rocks[J]. Advances in Water Resources,2017,107:160-179.
- [17]杨胜来,杭达震,孙蓉,等.CO2对原油的抽提及其对原油黏度的影响[J].中国石油大学学报(自然科学版),2009,33(4):85-88.YANG Shenglai,HANG Dazhen,SUN Rong,et al.CO2 extraction for crude oil and its effect on crude oil viscosity[J].Journal of China University of Petroleum(Edition of Natural Science),2009,33(4):85-88.
- [18] HUANG X,LI A,LI X,et al. Influence of typical core minerals on tight oil recovery during CO2 flooding using the nuclear magnetic resonance technique[J].Energy&Fuels,2019,33(8):7147-7154.
- [19] DAI C,CHENG R,SUN X,et al. Oil migration in nanometer to micrometer sized pores of tight oil sandstone during dynamic surfactant imbibition with online NMR[J]. Fuel, 2019, 245:544-553.
- [20] WANG H T,LUN Z M,LüC Y,et al.Nuclear magnetic resonance study on mechanisms of oil mobilization in tight sandstone reservoir exposed to carbon dioxide[J].SPE Journal,2018,23(3):750-761.
- [21] CHEN T,YANG Z M,DING Y H,et al.Waterflooding huff-npuff in tight oil cores using online nuclear magnetic resonance[J].Energies,2018,11(6):1524.
- [22]韩海水,李实,陈兴隆,等.CO2对原油烃组分膨胀效应的主控因素[J].石油学报,2016,37(3):392-398.HAN Haishui,LI Shi,CHEN Xinglong,et al. Main Control factors of carbon dioxide on swelling effect of crude hydrocarbon Components[J]. Acta Petrolei Sinica,2016,37(3):392-398.
- 致密油藏
- CO_2驱替
- 矿物
- 孔喉结构
- 核磁共振
- 注入压力
tight reservoir - CO_2 displacement
- mineral
- pore throat structure
- nuclear magnetic resonance(NMR)
- injection pressure