周立娟,林梅钦,李明远,郭继香
ZHOU Li-juan,et al.(Enhanced Oil Recovery Center of Chinese University of Petroleum,Beijing 102249,China)

• 1:中国石油大学提高采收率研究中心
• 2:中国石油大学提高采收率研究中心
• 3:中国石油大学提高采收率研究中心
• 4:中国石油大学提高采收率研究中心 北京102249

摘要(Abstract)：

采用界面张力仪和表面粘弹性仪研究了部分水解聚丙烯酰胺(HPAM)和疏水缔合聚合物(HAP)对油水界面性质的影响。研究结果表明,疏水缔合聚合物HAP可以显著降低煤油/模拟水体系界面张力,但对模拟油/模拟水体系界面张力影响较小;部分水解聚丙烯酰胺类聚合物CA对煤油/模拟水和模拟油/模拟水体系界面张力无明显影响。无论是煤油/模拟水体系还是模拟油/模拟水体系,随聚合物溶液浓度的增加,部分水解聚丙烯酰胺类聚合物CA均使体系界面剪切粘度逐渐增大。而疏水缔合聚合物HAP均使体系的界面剪切粘度先增加,后降低,而后再增加。部分水解聚丙烯酰胺(HPAM)相对分子质量较大时,HPAM溶液/模拟油体系的界面剪切粘度较大。
Interfacial properties of the polymer including partially hydrolyzed polyacrylamide(HPAM) and hydrophobically associating polymer(HAP) solution/model oil are studied respectively by dataphysics interfacial tension meter and SVR-S interfacial viscoelastic meter.Results show that,HAP can decrease interfacial tension of kerosene/formation water obviously,but impact little on that of model oil/formation water.The effects of polymer CA on interfacial tension of kerosene/formation water and model oil/ formation water are neither obvious.Polymer CA can increase interfacial shear viscosity of both kerosene/formation water and model oil/formation water as concentration of which was increased.When concentration of HAP is increased,interfacial shear viscosity of systems experiences a process of increasing at first,then decreasing,and then increasing.Interfacial shear viscosity of HPAM solution/model oil is higher when relative molecular weight of HPAM is bigger.

关键词(KeyWords)： 部分水解聚丙烯酰胺;疏水缔合聚合物;界面张力;界面剪切粘度
HPAM;hydrophobically associating polymer;interfacial tension;interfacial shear viscosity

Abstract:

Keywords:

基金项目(Foundation): 国家重点基础研究发展计划资助项目(课题编号:2005CB221305)

作者(Author): 周立娟,林梅钦,李明远,郭继香
ZHOU Li-juan,et al.(Enhanced Oil Recovery Center of Chinese University of Petroleum,Beijing 102249,China)

参考文献(References)：

• [1]葛广章,王勇进,王彦玲.聚合物驱及相关化学驱进展[J].油田化学,2001,18(3):282-284.
• [2]Ku like W M,Kn iewske R.Langfristige konfonnationsanderung vonmakromolekülen in i sung[J].Makromol.Chem,.1980,181:823-838.
• [3]L ibeyre R,Sarazin D,Francois J.Automatized photogon iod iffusom eterand coupling w ith automatized viscosim eter[J].Polym.Bu ll.,1981,4:53-60.
• [4]Ryles R G.Chem ical stab ility lim its of water-solube polym ers used inoil recovery processes[J].SPE Reservoi Engineering,1988,3(1):23-34.
• [5]Mu ller G,Fenyo J C,Selegny E J.H igh molecu lar weight hydrolyzedpolyacrylam ide.Ⅲ.E ffect of temperature on chem ical stab ility[J].Appl.Polym.Sci,.1980,25(4):627-633.
• [6]Evan i S,Rose G D.W ater-solube hydrophobe association polym ers[J].Polym.Mater.Sci.Eng,.1987,57:477-481.
• [7]Peiffer D G.Hydrophob ically associating polym ers and their interac-tions w ith rod-like m icelles[J].Polym er,1990,31:2352-2359.
• [8]A lain D,Dom in ique H.Synthesis and thermo-associative property inaqueous solution of graft copolym ers contain ing poly(N-isopropylac-rylam ide)side chains[J].Polym er,1999,40:4941-4951.
• [9]姜桂元,任鲲,徐春明.疏水缔合聚合物的合成及溶液性能研究[J].石油大学学报,2003,27(6):80-82.
• [10]M iller R,Wüstneck R,Kragel J.D ilational and shear rheology of ad-sorption layers at liqu id interfaces[R].Colloids and Surfaces A:physicochem ical and engineering aspects,1996,111:75-118.