近临界凝析气藏动态相态行为DYNAMIC PHASE BEHAVIORS OF A NEAR-CRITICAL CONDENSATE GAS RESERVOIR
侯大力,罗平亚,孙雷,乐潇,陈亮,卢斐
HOU Dali,LUO Pingya,SUN Lei,LE Xiao,CHEN Liang,LU Fei
摘要(Abstract):
以X油田S井近临界的地层流体为研究对象,利用可实时监测且可录像的DBR-PVT实验装置进行实验,为研究近临界复杂流体的相态特征及热力学模型提供基础数据。等组成膨胀实验测试了近临界流体在不同温度下的饱和压力,不同温度压力条件下的偏差因子、反凝析液量和临界点区间,并结合CMG相态模拟软件中1978年改进的PR状态方程拟合实测的泡/露点,得到完整的p-T相图和临界点;光学现象观测实验发现,近临界区流体具有"临界乳光"现象,流体从透明的金黄色渐变为浅棕色、红棕色,最后扩展为完全不透光的灰黑色;定容衰竭实验测试了衰竭过程中地层流体采出程度、反凝析液量、采出流体的组分变化和衰竭前后井流物p-T相图变化。
Taking the near-critical fluids of the formations of Well S of Oilfield X as the researched object,the experiment is conducted with the help of live-monitoring and video-recording DBR-PVT apparatus,thus the basic data for the studies of the phase characteristics of the near-critical complex fluids and thermodynamic model can be provided.Z-factosr at different temperatures and pressures,retrograde condensed liquid yield and the interval of the near-critical points are tested for the near-critical fluids in the constant composition expansion(CCE) experiment,and at the same time integrating with the improved PR state equation in 1978 in CMG phase-behavior simulating software,the actually measured bubble/dew point is matched,and then the complete p-T phase diagram and critical point are obtained;the observation experiment of the optical phenomenon finds out that the fluids near the nearcritical area possesses a "critical opalescence" phenomenon,the colors of the fluids gradually change from transparent golden yellow to shallow brown,red brown and in the end expand to completely opaque to black;the recovery of the formation fluids,yield of the retrograde condensed liquid,changes of the produced liquid compositions and p-T phase diagram of the fluids from the well before and after the depletion are tested in the process of the depletion.
关键词(KeyWords):
近临界;凝析气藏;动态;相态行为;p-T相图;无汞PVT仪;CMG相态模拟
near critical;condensate gas reservoir;dynamic;phase behavior;p-T phase diagram;no-mercury PVT instrument;CMG phase-behavior simulation
基金项目(Foundation): 国家重大专项“凝析气藏开发新技术研究”(2011B-1507)
作者(Author):
侯大力,罗平亚,孙雷,乐潇,陈亮,卢斐
HOU Dali,LUO Pingya,SUN Lei,LE Xiao,CHEN Liang,LU Fei
参考文献(References):
- [1]Shen Pingping,Luo Kai,Zheng Xitan,et aL Experimental study of near-critical behavior of rich gas condensate systems[R].SPE67285,2001.
- [2]胡永乐,罗凯,李相方,等.凝析、低渗气藏流体相态与渗流机理[M].北京:科学出版社,2010:40-45.
- [3]陈卫东,郭天民.近临界油气藏流体相行为研究的现状[J].石油勘探与开发,1996,23(1):76-78.
- [4]董平川,江同文,唐明龙,等.牙哈5凝析气藏开发方式优化[J].大庆石油地质与开发,2007,26(3):51-53.
- [5]燕良东,朱维耀,宋洪庆.多孔介质内高含蜡凝析气-液-固相变热力学模型分析[J].大庆石油地质与开发,2010,29(6):115-120.
- [6]李骞,李相方,赵习森,等.雅克拉凝析气藏生产气油比异常因素分析[J].大庆石油地质与开发,2011,30(5):79-83.
- [7]曹丽丽,董平川,李涛,等.凝析液析出对凝析气藏产能的影响[J].大庆石油地质与开发,2012,31(6):90-93.
- [8]Gil L,Mart'nez-Lo'pez F J',Artal M,et al.Volumetric behavior of the{CO_2(1)C_2H_6(2)}system in the subcritical(T=293.15K),critical,and supercritical(T=308.15 K)regions[J].J.Phys.Chem,2010,114(1):5447-5469.
- [9]Bazaev A R,Bazaev E A.The termodynamic properties of binary mixtures of technologically important substances in the near-and supercritical states[J].Russian Journal of Physical Chemistry B,2010,4(8):1178-1187.
- [10]Rasulov M S,Abdulagatov M I.PVTx measurements of water+npentane mixtures in critical and supererifical regions[J].J.Chem.Eng.Data,2010,55(1):3247-3261.
- [11]Rabezkii G M,Basaev A R,Abdulagatov M I,et al.PVTx measurements for water+toluene mixtures in the near-critical and supercritical regions[J].J.Chem.Eng.Data,2001,46(3):1610-1618.
- [12]Martin A,Mothes S,Mannsfeld G.Application of fluid opacity for determining the phase behavior of binary mixtures near their critical loci-CO_2 plus ethane and CO_2 plus propane[J].Fresenius J Anal Chem.,1999,364(2):638-640.
- [13]Kordikowski A,Robertsan G D,Aguiar-Ricardo A I,et al.Probing vapor/liquid equilibria of near-critical binary gas mixtures by acoustic measurements[J].J.Phys.Chem.,1996,100(1):9522-9526.
- [14]Llovell F,Vega L F.Global fluid phase equilibria and critical phenomena of selected mixtures using the crossover soft-SAFT equation[J].J.Phys.Chem.B,2006,110(4):1350-1362.
- [15]Sun Lixin,Zhan Honggang,Kiselev B S,et al.Predicting mix.rare phase equilibria and critical behavior using the SAFT-VRX Approach[J].J.Phys.Chem.B,2005,109(3):9047-9058.
- [16]Yan Wei,Wang Lukun,Guo Tianmin.A systematic experimental study on the phase behavior of complex fluid mixtures up to nearcritical region[J].Fluid Phase Equilibria,2001,190(1):159-178.
- [17]Yang T,Chen W D,Guo T M.Phase behavior of a near-critical reservoir fluid mixture[J].Fluid Phase Equilibria,1997,128(1):183-97.
- [18]Zheng Xitan,Sheng Pingping,Li Shi,et al.Experimental Investigation into near-critical phenomena of rich gas condensate systems[a].SPE 64712,2000.
- [19]Parral Coronado C-A,Remolina Eseobar J-C-M.Experimental study and calculations of the near critical behavior of a synthetic fluid in nitrogen injection[J].Ciencia Tecnologia y Futuro,2005,3(1):127-137.
- 近临界
- 凝析气藏
- 动态
- 相态行为
- p-T相图
- 无汞PVT仪
- CMG相态模拟
near critical - condensate gas reservoir
- dynamic
- phase behavior
- p-T phase diagram
- no-mercury PVT instrument
- CMG phase-behavior simulation