袁云龙,竺和平,石天宝
Yuan Yunlong; Zhu Heping and Shi Tianbao (Department of Chemistry; Shandong University);

• 1:山东大学化学系
• 2:山东大学化学系
• 3:山东大学化学系

摘要(Abstract)：

用苯酚滴定法研究醇类对非离子表面活性剂(辛基酚聚氧乙烯醚)亲水亲油平衡值的影响,所使用的醇有一元醇、二元醇和甘油。认为加入的醇增溶到胶束聚氧乙烯链“栅栏”之中,醇和水与表面活性剂中醚氧键的相互作用,可以看成广义酸碱的作用。实验结果与这一解释相符。
ABSTRACT The effect of alcohols on the hydrophile-lipophile basance (HLB) of nonionic surfactants (polyoxyethylene octy1 phenol ethers) is studied by method of phenol titration. The monohydric alcohols, glycols and glycerin are used. We consider that alcohols are solubilized into the polyoxyethylene chain "palisade", of the micelle. The interaction between alcohol(or water)and the polyether chain may be - explained hy interaction of generalized acid and generalized alkali. Experimental results are in agreement with this explaination.

关键词(KeyWords)：

Abstract:

Keywords:

基金项目(Foundation):

作者(Authors): 袁云龙,竺和平,石天宝
Yuan Yunlong; Zhu Heping and Shi Tianbao (Department of Chemistry; Shandong University);

DOI: 10.19597/j.issn.1000-3754.1988.04.009

参考文献(References)：

• [1] Hause. W.R.: New oil Recovery process. Porto. Engineer International Vol. SS, 1981.
• [2] Marszall.L.: J.coll. and Inter. sci., Vol. 60, No.3 (1077) P570.
• [3] Marszall L.: J. coll.and Inter. sci., Vol. 05, No.3(1978)P589.
• [4] Marsyall. L.: J.Am.oil them. Soc., Vol,S0, No.2(1982)P84.
• [5] 赵国玺:《表面活性剂物理化学》,北京大学出版社,1984年,P5.
• [6] 《有机化学》上册,人民教育出版社;1961年,P85。