马英华,唐善彧
Ma Yinghua (Petroleum University; Beijing ) ;

• 1:石油大学
• 2:中国石油天然气总公司勘探开发研究院 北京

摘要(Abstract)：

本文研究了两种表面活性剂(TRS10-80和天津ABS)盐水溶液与煤油之间的界面张力特性,提出了表面活性剂盐水溶液/煤油体系中动态界面张力产生的机理,讨论了表面活性剂对油的增溶作用对界面张力的影响。经过长期预平衡的表面活性剂盐水溶液/煤油体系仍然存在明显的功态界面张力特性。
: The interfacial tension behavior between kerosene and two surfactant brine solutions(TRS10-80 and Tianjin ABS) was studied with the Spinning-Drop technigue in this paper.A mechanism for the formation of the dynamic interfa-cial tension in surfactant brine solution/kerosene systems was proposed. The effect of the solubilization of surfactants on the interfacial tension between oil and water was also discussed.The experiment data showed that the time depen-dence of inlerfacial tensions in the pre-equilibrated ( at least 10 days ) surf-actant brinesoluton/kerosene systems still exist.

关键词(KeyWords)： 表面活性剂;界面张力;水溶液;动态界面张力(增);增溶作用(增)
: Surfactant, Dynamic interfacial tension, Solubilization

Abstract:

Keywords:

基金项目(Foundation):

作者(Authors): 马英华,唐善彧
Ma Yinghua (Petroleum University; Beijing ) ;

DOI: 10.19597/j.issn.1000-3754.1991.02.012

参考文献(References)：

• 〔1〕Foster,W,R, ,J,Pet,Technol.25: 205 (1973) .
• 〔2〕Reishery,J,and Doscher, T,M,, Producers Monthly, Nov,1956, pp45-50.
• 〔3〕Campbell, T,C,, SPE 6514.
• 〔4〕McCaffery,F,G,,J,Can .Petrol,Techol..1976,15,71-74.
• 〔5〕Harkins, W,D, and Zollman, H,J,Amer Chem,Soc.Jan,1926,69-80.
• 〔6〕England D,C,and Berg,J,C, AICHE Sour,March 1971,313-322.
• 〔7〕Rwbin,E,and Radke.C,H,, Chem.Eng,Sci,35,1980,1129-1130.
• 〔8〕Sharma.M.M,Jang.L.K.and Yen,T,F.,SPE/ DOE 12669.
• 〔9〕Borwandar.R,P,and Wason,D.T. ,AICHE.J,March 1986 455-466.
• 〔10〕Capelle,A.,"Surface Phenomena in Enhanced Oil Recovery" Ed,by. D,o.Shan,1979.p.229.
• 〔11〕Vonnegut .B.,Rev.Sci.Instrum.. 1942,13 p.6.
• 〔l2〕Princen,H.M..Zia.I.Y Z.,and Mason S,G,,J,C,olloid Interface Sci,,1967,23,P 99.
• 〔13〕Chan,K,S,.and shan D,O,in:"Surface Phenomena in Enhanced Oil Recovery" , Ed.byD,O,Shan,1979 ,p,53.