改善疏水缔合聚合物油藏适应性方法及其效果ADAPTABILITY IMPROVING METHOD AND ITS APPLIED EFFECTS FOR THE HYDROPHOBICALLY ASSOCIATED POLYMER TO THE OIL RESERVOIRS
王研,王军,王洪志,谢俊秋,张玉梅,卢祥国
WANG Yan,WANG Jun,WANG Hongzhi,XIE Junqiu,ZHANG Yumei,LU Xiangguo
摘要(Abstract):
为适应高矿化度溶剂水配制聚合物溶液实际需求,以油藏工程理论为指导,以仪器检测和物理模拟为技术手段,开展了疏水缔合型聚合物溶液视黏度及其影响因素研究。评价了表面活性剂抑制和促进聚合物分子链间缔合作用效果,进行了表面活性剂与缔合聚合物组合和注入方式对聚合物溶液渗流压力影响物理模拟研究。结果表明:非离子型表面活性剂(DWS)可以抑制聚合物分子链间的缔合作用,重烷基苯石油磺酸盐(HABS)表面活性剂可以促进聚合物分子链间缔合作用;采取"聚合物/DWS表面活性剂混合液+HABS表面活性剂溶液"段塞组合和交替注入方式,可以抑制聚合物溶液注入油藏过程中聚合物分子链间的缔合作用,这不仅改善了缔合聚合物溶液的注入能力,而且增强了其深部液流转向效果。
In order to meet the actual requirements of the polymer solution prepared by high-salinity solvent water,guided by the theories of oil reservoir engineering,the studies on the apparent viscosity of hydrophobically associated polymer solution and its influencing factors are conducted with the help of technical methods of instrumental measures and physical simulation.The associating effects among the polymer molecular chains constrained and enhanced by the surfactant are evaluated,and moreover the researches on the physical simulation of the influences of the combined forms and injected methods of the above binary flooding agents on the flow pressure of the polymer solution are engaged.The results show that the nonionic surfactant(DWS) can restrain the association among the polymer,HABS surfactant can improve the above action;adopting the combining and alternative injecting methodsbetween the mixed solution of polymer/DWS surfactant and HABS surfactant solution slug,the association among the polymer molecular chains can be inhibited in the process of the polymer solution,thus the injection capacity of the associated polymer solution can be promoted,but also the diverting effects of the deep solution can be improved and enhanced.
关键词(KeyWords):
缔合型聚合物;表面活性剂;缔合作用;黏度;渗流特性
associated polymer;surfactant;association;viscosity;flow characteristic
基金项目(Foundation): “十二五”油气国家重大专项“高效深部液流转向与调驱和精细分层注采技术”(2011ZX05010-003)
作者(Author):
王研,王军,王洪志,谢俊秋,张玉梅,卢祥国
WANG Yan,WANG Jun,WANG Hongzhi,XIE Junqiu,ZHANG Yumei,LU Xiangguo
参考文献(References):
- [1]王德民,程杰成,吴军政,等.聚合物驱油技术在大庆油田的应用[J].石油学报,2005,26(1):74-78.
- [2]周守为,韩明,向问陶,等.渤海油田聚合物驱提高采收率技术研究及应用[J].中国海上油气,2006,18(6):386-389.
- [3]钟仪华,王昱.特高含水油田开发动态指标及影响因素[J].大庆石油地质与开发,2011,30(1):91-94.
- [4]路新宇,卢祥国,邓庆军,等.大庆油田三类油层化学驱增油效果评价及其机理分析[J].大庆石油地质与开发,2011,30(1):131-136.
- [5]唐晓旭,王闯,卢祥国,等.聚表剂溶液性能及其驱油机理[J].大庆石油地质与开发,2011,30(3):144-149.
- [6]卢祥国,王伟,孙刚.电解质对聚合物溶液渗流特性影响及作用机理研究[J].大庆石油地质与开发,2007,26(1):104-108
- [7]Lu Xiangguo,Wang Xiaoyan,Jiang Weidong.Experimental study on the molecular dimention and configuration of polymer and it How characteristics from electrolyte effect[J].Chinese Journal of Chemistry,2009,27(4):839-845.
- [8]王晓燕,卢祥国,姜维东.正负离子和表面活性剂对水解聚丙烯酰胺分子线团尺寸的影响及其作用机理[J].高分子学报,2009(12):1259-1265.
- [9]冯玉军.疏水缔合水溶性聚合物溶液结构及其对溶液流变性影响的研究[D].南充:西南石油学院,1999.
- [10]卢祥国,高振环,闫文华,等.人造岩心渗透率影响因素试验研究[J].大庆石油地质与开发,1994,13(4):53-55.