大庆油田萨中化学驱注入井附近地带油层堵塞机理及解堵剂配方优化Blocking mechanism and blockage removal agent formula for oil layer near chemical flooding injection wells in Sazhong area of Daqing Oilfield
胡俊卿
HU Junqing
摘要(Abstract):
化学驱的规模应用,不断刷新着大庆油田采收率极限,成为油田持续有效开发的重要技术,但随着化学驱注剂量增加,地层近井地带堵塞严重,部分井欠注现象日益突出,影响区块开发效果。针对洗井吐液中大量的胶团导致近井地带堵塞的问题,利用仪器检测和物理化学分析等手段对化学驱返吐的堵塞物进行分析,明确堵塞物成分并揭示堵塞机理。结果表明:聚合物胶团主要成分是有机物,夹杂金属离子和垢质,呈高黏无弹性、胶联状排列的致密结构;Fe~(3+)和Al~(3+)是导致聚合物形成胶团的主要原因,污水中的细菌发生氧化还原反应腐蚀管线产生Fe~(3+),生成胶团临界质量浓度为1.5 mg/L;碱溶蚀地层产生Al~(3+),生成胶团临界质量浓度为1.375 mg/L;针对堵塞物成分开展解堵剂优化研究,形成了采油1-1型和采油1-2型2种解堵剂,现场实施10口井,平均单井注入压力下降了1.4 MPa,平均单井日增注量为23 m~3,累计增注量为973 m~3。研究成果可有效指导化学驱欠注井治理,对化学驱提质增效具有重要意义。
Large-scale application of chemical flooding has continuously broken recovery limit of Daqing Oilfield and become an important technology for sustainable effective development of the oilfield.However,the increase of chemical injection volume causes serious blockage of near-well formation and increasingly under-injection phenomenon of some wells,affecting development effect of the block.In view of the problem that a large number of micelles appear in backwash fluid,which leads to blockage in near-wellbore zone,instrument detection and physical and chemical analysis are performed to analyze the blockage of chemical flooding backwash,determine blockage composition and reveal blocking mechanism.The results shows that the main component of polymer micelles is organic matter,which is mixed with metal ions and scale,and has dense structure of high viscosity,inelastic and gelatinous arrangement.Fe~(3+)ions and Al~(3+)ions are main causes for polymer forming micelles.The bacteria in produced water corrode the pipeline by oxidation-reduction reaction to produce Fe~(3+)ions,and critical concentration of micelles is1.5 mg/L.Al~(3+)ions are generated from alkaline solution formation,and critical concentration of generated micelles is1.375 mg/L.According to the composition of blockage material,blockage removal agent is optimized,and 2 kinds of agent including Oil Production 1-1 type and Oil Production 1-2 type are formed.10 wells are implemented on site,with average injection pressure of single well decreased by 1.4 MPa,average daily injection of single well increased by 23 m~3,and cumulative injection increased by 973 m~3.The research can guide the treatment of under-injection wells in chemical flooding,and have significance for improving the quality and efficiency of chemical flooding.
关键词(KeyWords):
化学驱;近井地带堵塞;胶团;形成机理;解堵方法;萨中
chemical flooding;near wellbore blockage;micelle;formation mechanism;blockage removal method;Sazhong area
基金项目(Foundation): 中国石油天然气股份有限公司重大科技专项“三次采油提高采收率关键技术”(2021DJ16)
作者(Author):
胡俊卿
HU Junqing
DOI: 10.19597/j.issn.1000-3754.202210062
参考文献(References):
- [1]计秉玉.国内外油田提高采收率技术进展与展望[J].石油与天然气地质,2012,33(1):111-117.JI Bingyu. Progress and prospects of enhanced oil recovery technologies at home and abroad[J].Oil&Gas Geology,2012,33(1):111-117.
- [2]张赫,单高军,杜庆龙,等.大庆长垣油田特高含水后期水驱开发技术难题及其对策[J].大庆石油地质与开发,2022,41(4):60-66.ZHANG He, SHAN Gaojun, DU Qinglong, et al. Technical challenges and solutions of water flooding development in late stage of ultra-high water cut in Placanticline oilfield in Daqing[J]. Petroleum Geology&Oilfield Development in Daqing,2022,41(4):60-66.
- [3]孙龙德,伍晓林,周万富,等.大庆油田化学驱提高采收率技术[J].石油勘探与开发,2018,45(4):636-645.SUN Longde,WU Xiaolin,ZHOU Wanfu,et al. Technologies of enhancing oil recovery by chemical flooding in Daqing Oilfield,NE China[J].Petroleum Exploration and Development,2018,45(4):636-645.
- [4]廖广志,王强,王红庄,等.化学驱开发现状与前景展望[J].石油学报,2017,38(2):196-207.LIAO Guangzhi, WANG Qiang, WANG Hongzhuang, et al.Chemical flooding development status and prospect[J]. Acta Petrolei Sinica,2017,38(2):196-207.
- [5]沈燕来,刘德华,吉延章,等.渤海埕北油田、绥中36-1油田注水井堵塞机理研究[J].石油钻采工艺,1998,20(1):90-93.SHEN Yanlai, LIU Dehua, JI Yanzhang, et al. The plugging mechanism of water injection wells in Chengbei and Suizhong 36-1Oilfield of Bohai[J]. Oil Drilling&Production Technology,1998,20(1):90-93.
- [6]张晓冉,孟祥海,高建崇,等.海上Z油田二元驱注入井解堵体系室内实验研究[J].精细与专用化学品,2019,27(5):22-25.ZHANG Xiaoran, MENG Xianghai, GAO Jianchong, et al.Evaluation of plug removal system of binary flooding injection wells in offshore Z oilfield[J]. Fine and Specialty Chemicals,2019,27(5):22-25.
- [7]李玉光,邢希金,李莹莹,等.针对渤海A油田注水井堵塞的解堵增注液研究[J].石油天然气学报,2013,35(11):132-135.LI Yuguang,XING Xijin,LI Yingying,et al. Research of blocking removal and augmented injection fluid for water injection wells in Bohai A Oilfield[J]. Journal of Oil and Gas Technology,2013,35(11):132-135.
- [8]刘盈,陈安胜,王建海,等.聚合物驱油藏油井堵塞机制与防治[J].油田化学,2022,39(3):431-437.LIU Ying, CHEN Ansheng, WANG Jianhai, et al. Plugging mechanism and prevention of oil well in polymer flooding reservoir[J].Oilfield Chemistry,2022,39(3):431-437.
- [9]赵林,高申领,陈渊,等.砂岩油藏聚合物堵塞机理及解堵方法研究[J].特种油气藏,2022,29(3):156-161.ZHAO Lin,GAO Shenling,CHEN Yuan,et al. Study on polymer plugging mechanism and plug removal method in sandstone reservoirs[J]. Special Oil&Gas Reservoirs,2022,29(3):156-161.
- [10]蔡莹莹,陈小凯,曾双红,等.聚驱/调驱井解堵增注技术研究与应用[J].化学工程师,2017,31(5):60-63.CAI Yingying, CHEN Xiaokai, ZENG Shuanghong, et al.Research and application of polymer broken down and water injectivity technology[J]. Chemical Engineer, 2017, 31(5):60-63.
- [11]鲍彦锋,郑凯亓,高建崇,等. JZ9-3油田注入井堵塞物组分分析及形成机理研究[J].化学工程师,2022,36(8):63-67.BAO Yanfeng,ZHENG Kaiqi,GAO Jianchong,et al. Composition analysis and formation mechanism study of plug in injection well of JZ9-3 Oilfield[J].Chemical Engineer,2022,36(8):63-67.
- [12]张丽莹.聚合物注入井加深洗井技术[J].油气田地面工程,2014,33(5):96.ZHANG Liying. Deepening well flushing technology for polymer injection wells[J]. Oil-Gas Field Surface Engineering, 2014,33(5):96.
- [13]高尚,刘义刚,兰夕堂,等.渤海油田注聚合物井堵塞物组分分析及相互作用机理[J].油田化学,2020, 37(2):340-343.GAO Shang,LIU Yigang,LAN Xitang,et al. Component analysis and interaction mechanism of fouling in polymer flooding well in Bohai Oilfield[J]. Oilfield Chemistry, 2020, 37(2):340-343.
- [14]付美龙,张志远,侯宝峰,等.河南油田注聚井聚合物堵塞机理及防治技术[J].长江大学学报(自然科学版),2021,18(3):37-48.FU Meilong, ZHANG Zhiyuan, HOU Baofeng, et al. Polymer plugging mechanism and prevent technology of polymer injection wells in Henan Oilfield[J]. Journal of Yangtze University(Natural Science Edition),2021,18(3):37-48.
- [15]邹剑. SZ36-1油田注聚井和聚驱受益油井堵塞物的组成及成因对比分析[J].石油与天然气化工,2019,48(5):77-82.ZOU Jian. Comparisons of component and formation mechanism of blockages in polymer flooding injection well and response well in SZ36-1 oilfield[J].Chemical Engineering of Oil&Gas,2019,48(5):77-82.
- [16]张玉,王凤,魏丽敏,等.国内外化学驱技术标准对比[J].油田化学,2021,38(4):727-731.ZHANG Yu,WANG Feng,WEI Limin,et al.Comparison of domestic and international standards for chemical flooding[J].Oilfield Chemistry,2021,38(4):727-731.
- [17]计秉玉,王友启,张莉.基于地质储量结构变化的采收率演变趋势[J].石油与天然气地质,2020,41(6):1257-1262.JI Bingyu, WANG Youqi, ZHANG Li. Research on overall recovery rate variations of dynamically changing OOIP[J].Oil&Gas Geology,2020,41(6):1257-1262.
- [18]郑俊德,张英志,任华,等.注聚合物井堵塞机理分析及解堵剂研究[J].石油勘探与开发,2004,31(6):108-111.ZHENG Junde,ZHANG Yingzhi,REN Hua,et al.Blockage mechanism and blockage reducer for polymer-injection well[J].Petroleum Exploration and Development,2004,31(6):108-111.
- [19]周万富,赵敏,王鑫,等.注聚井堵塞原因[J].大庆石油学院学报,2004,28(2):40-42.ZHOU Wanfu,ZHAO Min,WANG Xin,et al. Analysis of the polymer injection wells plugging[J]. Journal of Daqing Petroleum Institute,2004,28(2):40-42.
- [20]吕凯,戴彩丽,张若然,等.疏水缔合聚合物在地层多孔介质吸附特性研究[J].油田化学,2010,27(4):391-394.LüKai,DAI Caili,ZHANG Ruoran,et al. Investigations of adsorption rules of hydrophobically associating polymer in the porus medium[J]. Oilfield Chemistry,2010,27(4):391-394.
- [21]谢朝阳,李国,王鑫,等.大庆油田注聚井解堵增注技术[J].大庆石油地质与开发,2003,22(6):57-59.XIE Chaoyang,LI Guo,WANG Xin,et al. The shutoff removing and injection increasing technique of polymer injection well in Daqing Oilfield[J].Petroleum Geology&Oilfield Development in Daqing,2003,22(6):57-59.
- [22]周博,董长银,王力智,等.含聚合物疏松砂岩岩心出砂形态微观模拟实验[J].断块油气田,2021,28(6):848-853.ZHOU Bo,DONG Changyin,WANG Lizhi,et al. Microscopic simulation experiments on sand production morphology of polymerbearing unconsolidated sandstone cores[J]. Fault-Block Oil&Gas Field,2021,28(6):848-853.
- 化学驱
- 近井地带堵塞
- 胶团
- 形成机理
- 解堵方法
- 萨中
chemical flooding - near wellbore blockage
- micelle
- formation mechanism
- blockage removal method
- Sazhong area