古龙页岩亚微米级孔隙中原油密度与分布的原位定量观测方法In??situ quantitative observation method for oil density and distribution in submicron??scale pores of Gulong shale
高波,张刘平,冯子辉,陈凤祥,李照阳,邵红梅,黄晓天
GAO Bo,ZHANG Liuping,FENG Zihui,CHEN Fengxiang,LI Zhaoyang,SHAO Hongmei,HUANG Xiaotian
摘要(Abstract):
为查明古龙页岩中轻质油的分布,应用激光共聚焦冷冻观测技术,系统分析了松辽盆地的原油样品,建立了反射光-长短波荧光多重扫描图R/G强度比与原油密度之间的关系和古龙页岩中轻质油、中质油和重质组分(包括重质油、胶质沥青质和生烃母质)的原位观测方法。结果表明:松辽盆地古龙凹陷S18井青山口组页岩油多呈不规则形状、斑块状和星点状;轻质油的含量明显高于中质油和重质组分,轻/(中+重)面积比的平均值高达8.6。在观测井段,轻质油主要富集于纹层状-层状页岩。根据轻质油和轻/(中+重)面积比的分布情况,评价了油层组。总体上,该井Q_9油层组优于Q_6―Q_7油层组,Q_6―Q_7油层组又优于Q_1―Q_2油层组。通过系统观测与研究页岩中轻质油的分布,可为优化勘探开发目标,优选水平井压裂井段提供新的重要依据。
In order to identify the distribution of light oil in Gulong shale,laser scanning confocal freezing observation technology is used to systematically analyze oil samples from Songliao Basin.The relationship between R/G intensity ratio of reflection light-long/shortwave fluorescence multiple scanning images and oil density is established,as well as an in-situ observation method for light oil,medium oil and heavy oil components(including heavy oil,resin asphaltene and hydrocarbon-generating parent material) in Gulong shale.The results show that shale oil in Qingshankou Formation of Well S18 in Gulong Sag of Songliao Basin mostly presents to be irregular,patchy and sporadic.The content of light oil is significantly higher than that of medium oil and heavy components,with an average area ratio light/(medium+heavy) oil up to 8.6.In observed well intervals,light oil is mainly enriched in laminated-layered shale.Based on the area ratio distribution of light oil and the light/(medium+heavy),reservoir members are evaluated.In general,Q_9 reservoir member in this well is superior to Q_6-Q_7 reservoir members,and Q_6-Q_7reservoir members are superior to Q_1-Q_2 reservoir members.Systematic observation and study of the distribution of light oil in the shale provide new important basis for optimizing exploration and development targets and selecting fracturing horizontal well intervals.
关键词(KeyWords):
页岩油;轻质油;激光扫描共聚焦显微镜;冷台;含油性;岩性;松辽盆地
shale oil;light oil;laser scanning confocal microscope;cold stage;oil-bearing properties;lithology;Songliao Basin
基金项目(Foundation): 黑龙江省重点研发计划“多资源协同陆相页岩油绿色开采全国重点实验室”(JD2023GJ02);; 黑龙江省揭榜挂帅科技项目“古龙页岩油碳同位素分馏效应研究”(DQYT-2022-JS-753);; 中国石油-北京大学基础研究项目“中低成熟度页岩油超临界水改质研究”(22-2-1)
作者(Author):
高波,张刘平,冯子辉,陈凤祥,李照阳,邵红梅,黄晓天
GAO Bo,ZHANG Liuping,FENG Zihui,CHEN Fengxiang,LI Zhaoyang,SHAO Hongmei,HUANG Xiaotian
DOI: 10.19597/J.ISSN.1000-3754.202410038
参考文献(References):
- [1]金之钧,白振瑞,高波,等.中国迎来页岩油气革命了吗?[J].石油与天然气地质,2019,40(3):451-458.JIN Zhijun,BAI Zhenrui,GAO Bo,et al. Has China ushered in the shale oil and gas revolution?[J]. Oil&Gas Geology,2019,40(3):451-458.
- [2]金之钧,张谦,朱如凯,等.中国陆相页岩油分类及其意义[J].石油与天然气地质,2023,44(4):801-819.JIN Zhijun,ZHANG Qian,ZHU Rukai,et al.Classification of lacustrine shale oil reservoirs in China and its significance[J].Oil&Gas Geology,2023,44(4):801-819.
- [3]郭旭升,马晓潇,黎茂稳,等.陆相页岩油富集机理探讨[J].石油与天然气地质,2023,44(6):1333-1349.GUO Xusheng, MA Xiaoxiao, LI Maowen, et al. Mechanisms for lacustrine shale oil enrichment in Chinese sedimentary basins[J]. Oil&Gas Geology,2023,44(6):1333-1349.
- [4]鲁锋,李照阳,杨召,等.激光扫描共聚焦显微分析技术表征页岩亚微米级孔隙中的含油性:以准噶尔盆地芦草沟组页岩为例[J].石油实验地质,2023,45(1):193-202.LU Feng,LI Zhaoyang,YANG Zhao,et al. Characterization of oil-bearing properties in sub-micron shale pores by laser scanning confocal microscopy technology:A case study of shale in Lucao??gou Formation,Junggar Basin[J]. Petroleum Geology&Exper??iment,2023,45(1):193-202.
- [5]崔宝文,陈春瑞,林旭东,等.松辽盆地古龙页岩油甜点特征及分布[J].大庆石油地质与开发,2020,39(3):45-55.CUI Baowen,CHEN Chunrui,LIN Xudong,et al. Characteris??tics and distribution of sweet spots in Gulong shale oil reserviors of Songliao Basin[J]. Petroleum Geology&Oilfield Development in Daqing,2020,39(3):45-55.
- [6]李明,王民,张金友,等.中国典型盆地陆相页岩油组分评价及意义[J].石油与天然气地质,2023,44(6):1479-1498.LI Ming,WANG Min,ZHANG Jinyou,et al. Evaluation of the compositions of lacustrine shale oil in China’s typical basins and its implications[J]. Oil&Gas Geology, 2023, 44(6):1479-1498.
- [7]孙龙德,王小军,冯子辉,等.松辽盆地古龙页岩纳米孔缝形成机制与页岩油富集特征[J].石油与天然气地质,2023,44(6):1350-1365.SUN Longde, WANG Xiaojun, FENG Zihui, et al. Formation mechanisms of nano-scale pores/fissures and shale oil enrichment characteristics for Gulong shale,Songliao Basin[J].Oil&Gas Geology,2023,44(6):1350-1365.
- [8]白斌,戴朝成,侯秀林,等.松辽盆地白垩系青山口组页岩层系非均质地质特征与页岩油甜点评价[J].石油与天然气地质,2023,44(4):846-856.BAI Bin,DAI Chaocheng,HOU Xiulin,et al. Geological het??erogeneity of shale sequence and evaluation of shale oil sweet spots in the Qingshankou Formation,Songliao Basin[J]. Oil&Gas Geology,2023,44(4):846-856.
- [9]白斌,朱如凯,吴松涛,等.非常规油气致密储层微观孔喉结构表征新技术及意义[J].中国石油勘探,2014,19(3):78-86.BAI Bin, ZHU Rukai, WU Songtao, et al. New micro-throat structural characterization techniques for unconventional tight hy??drocarbon reservoir[J]. China Petroleum Exploration, 2014,19(3):78-86.
- [10]邵红梅,李照阳,王继平,等.激光扫描共聚焦显微镜冷冻观测技术表征页岩亚微米孔隙中的含油性:以松辽盆地古龙凹陷青山口组页岩油为例[J/OL].大庆石油地质与发,[2024-12-06]. https://doi. org/10.19597/J. ISSN. 1000-3754.202404008.SHAO Hongmei,LI Zhaoyang,WANG Jiping,et al. Character??ization of oil-bearing properties in sub-micron shale pores by laser scanning confocal microscopy freezing observation technology:Taking shale oil of Qingshankou Formation in Gulong Sag of Songliao Basin as an example[J/OL]. Petroleum Geology&Oil??field Development in Daqing,[2024-12-06]. https://doi. org/10.19597/J.ISSN.1000-3754.202404008.
- [11]冯子辉,霍秋立,王雪,等.青山口组一段烃源岩有机地球化学特征及古沉积环境[J].大庆石油地质与开发,2015,34(4):1-7.FENG Zihui,HUO Qiuli,WANG Xue,et al. Organic geochem??ical characteristics and paleosedimentary environments of the source rocks in Member 1 of Qingshankou Formation[J]. Petro??leum Geology&Oilfield Development in Daqing, 2015, 34(4):1-7.
- [12]张刘平,李照阳.一种用于激光扫描显微镜荧光观测的冷台及使用方法:202211009988.9[P].2022-08-23.ZHANG Liuping,LI Zhaoyang. A cold stage and method for cryoobservation with laser scanning confocal microscope:202211009988.9[P]. 2022-08-23.
- [13]冯子辉,柳波,邵红梅,等.松辽盆地古龙地区青山口组泥页岩成岩演化与储集性能[J].大庆石油地质与开发,2020,39(3):72-85.FENG Zihui, LIU Bo, SHAO Hongmei, et al. The diagenesis evolution and accumulating performance of the mud shale in Qing??shankou Formation in Gulong area,Songliao Basin[J]. Petro??leum Geology&Oilfield Development in Daqing, 2020, 39(3):72-85.
- [14]柳波,蒙启安,付晓飞,等.松辽盆地白垩系青山口组一段页岩生、排烃组分特征及页岩油相态演化[J].石油与天然气地质,2024,45(2):406-419.LIU Bo,MENG Qi’an,FU Xiaofei,et al. Composition of gener??ated and expelled hydrocarbons and phase evolution of shale oil in the 1st member of Qingshankou Formation,Songliao Basin[J].Oil&Gas Geology,2024,45(2):406-419.
- [15]吕丹,王华建,李罡,等.松辽盆地青山口组页岩沉积水体环境演变的古生物学证据[J].石油与天然气地质,2023,44(4):857-868.L??Dan, WANG Huajian, LI Gang, et al. Paleobiological evi??dence of the paleowater environment evolution during deposition of the Qingshankou shale in the Songliao Basin[J]. Oil&Gas Geology,2023,44(4):857-868.
- [16]张天舒,朱如凯,蔡毅,等.松辽盆地古龙凹陷白垩系青山口组页岩层序等时格架下的有机质分布规律[J].石油与天然气地质,2023,44(4):869-886.ZHANG Tianshu,ZHU Rukai,CAI Yi,et al. Distribution of or??ganic matter in the Qingshankou Formation Shale, Gulong Sag,Songliao Basin observed within an isochronous sequence strati??graphic framework[J]. Oil&Gas Geology, 2023, 44(4):869-886.
- [17]何文渊,柳波,张金友,等.松辽盆地古龙页岩油地质特征及关键科学问题探索[J].地球科学,2023,48(1):49-62.HE Wenyuan,LIU Bo,ZHANG Jinyou,et al. Geological char??acteristics and key scientific and technological problems of Gulong shale oil in Songliao Basin[J]. Earth Science,2023,48(1):49-62.
- [18]杨沛,胡望水,崔莺莺,等.基于多尺度CT扫描的长岭凹陷青一段储层特征及渗流机理[J].断块油气田,2025,32(2):211-220.YANG Pei,HU Wangshui,CUI Yingying,et al. Reservoir char??acteristics and seepage mechanism of Qing 1 Member in Chan??gling Sag based on CT scanning[J]. Fault-Block Oil&Gas Field,2025,32(2):211-220.
- [19]陈鸿安,付兰清.松辽盆地青山口组页岩油储层孔隙结构对渗吸特征影响[J].特种油气藏,2025,32(3):94-103.CHEN Hongan,FU Lanqing. Impact of pore structure on imbibi??tion characteristics in Qingshankou Formation shale oil reservoirs,Songliao Basin[J]. Special Oil&Gas Reservoirs, 2025, 32(3):94-103.
- [20]霍凤龙.古龙地区泥岩裂缝油藏成藏条件及地球物理特征研究[D].杭州:浙江大学,2012.HUO Fenglong. Fractured mudstone reservior forming condition and its geophysical characteristics in Qijia-Gulong area[D].Hangzhou:Zhejiang University,2012.
- [21]高波,何文渊,冯子辉,等.松辽盆地古龙页岩岩性、物性、含油性特征及控制因素[J].大庆石油地质与开发,2022,41(3):68-79.GAO Bo,HE Wenyuan,FENG Zihui,et al. Lithology,physi??cal property,oil-bearing property and their controlling factors of Gulong shale in Songliao Basin[J]. Petroleum Geology&Oilfield Development in Daqing,2022,41(3):68-79.
- [22]邵红梅,高波,洪淑新,等.页岩油储层实验技术进展及应用:以松辽盆地古龙地区为例[J].大庆石油地质与开发,2020,39(3):97-106.SHAO Hongmei,GAO Bo,HONG Shuxin,et al. Progress and application of the experimental technologies for the shale oil reser??voirs:A case study on Gulong area in Songliao Basin[J]. Petro??leum Geology&Oilfield Development in Daqing, 2020, 39(3):97-106.
- 页岩油
- 轻质油
- 激光扫描共聚焦显微镜
- 冷台
- 含油性
- 岩性
- 松辽盆地
shale oil - light oil
- laser scanning confocal microscope
- cold stage
- oil-bearing properties
- lithology
- Songliao Basin
- 高波
- 张刘平
- 冯子辉
- 陈凤祥
- 李照阳
- 邵红梅
- 黄晓天
GAO Bo - ZHANG Liuping
- FENG Zihui
- CHEN Fengxiang
- LI Zhaoyang
- SHAO Hongmei
- HUANG Xiaotian
- 高波
- 张刘平
- 冯子辉
- 陈凤祥
- 李照阳
- 邵红梅
- 黄晓天
GAO Bo - ZHANG Liuping
- FENG Zihui
- CHEN Fengxiang
- LI Zhaoyang
- SHAO Hongmei
- HUANG Xiaotian