适合中深层稠油油藏的两亲性稠油乳化降黏剂的制备及性能评价Preparation and performance evaluation of amphiphilic emulsified viscosity reducer for medium-deep heavy oil reservoirs
何永清,鲁霖懋,周其勇,秦嘉敏,陈磊
HE Yongqing,LU Linmao,ZHOU Qiyong,QIN Jiamin,CHEN Lei
摘要(Abstract):
为了有效降低稠油黏度,进一步提高稠油油藏热采开发后的采收率,以甲基丙烯酰胺MAA、二甲基二烯丙基氯化铵DMDAAC和有机硅表面活性单体T-Si为原料,制备了一种适合稠油油藏化学降黏开采用的MDT-1型两亲性稠油乳化降黏剂,并对其结构进行了表征,评价其综合性能。结果表明:当MDT-1型乳化降黏剂质量浓度为5 g/L时,对目标稠油样品的降黏率可以达到99.22%;对目标稠油的静态洗油率可以达到68.9%;注入1 PV质量浓度为5 g/L的MDT-1型乳化降黏剂后,油藏采收率可比水驱阶段提高37.08百分点;MDT-1型乳化降黏剂与稠油所形成的油水乳状液稳定性较差(120 min脱水率大于80%),乳化降黏后不会增加破乳脱水的工作难度。MDT-1型乳化降黏剂具有良好的界面活性、润湿性、降黏性、驱油性,且洗油效果较好,能够进一步提高稠油油藏热采采收率。研究成果对中深层稠油油藏的高效开发具有一定的指导意义。
In order to effectively reduce heavy oil viscosity and further improve recovery factor after thermal recovery of heavy oil reservoirs, taking methylacrylamide(MAA), dimethyldiallylammonium chloride(DMDAAC) and organosilicon surfactant monomers(T-Si) as raw materials, amphiphilic emulsified viscosity reducer MDT-1 for chemical viscosity reduction of heavy oil reservoirs is prepared with its structure characterized for comprehensive performance evaluation. The results show that MDT-1 with mass concentration of 5 g/L gets viscosity reduction rate of 99.22% and static oil washing rate of 68.9% of target heavy oil sample. After injecting 1 PV MDT-1 solution with mass concentration of 5 g/L, recovery factor of reservoirs is increased by 37.08 percentage points of water drive stage. Oil-water emulsion formed by emulsified viscosity reducer MDT-1 and heavy oil has poor stability(dehydration rate in 120 min is >80%), without increasing difficulty of demulsification and dehydration treatment after emulsified viscosity reduction. Emulsified viscosity reducer MDT-1 further enhances thermal recovery of heavy oil reservoirs for its high interfacial activity, wettability, viscosity reduction, oil displacement performance, and good oil washing effect.The research results have certain guiding significance for the efficient development of medium-deep heavy oil reservoirs.
关键词(KeyWords):
稠油油藏;乳化降黏剂;两亲型聚合物;界面活性;破乳脱水
heavy oil reservoir;emulsified viscosity reducer;amphiphilic polymer;interfacial activity;demulsification and dehydration
基金项目(Foundation): 国家科技重大专项子课题“稠油油田高效开发新技术研究”(2017ZX05025-002)
作者(Author):
何永清,鲁霖懋,周其勇,秦嘉敏,陈磊
HE Yongqing,LU Linmao,ZHOU Qiyong,QIN Jiamin,CHEN Lei
DOI: 10.19597/j.issn.1000-3754.202211015
参考文献(References):
- [1]方吉超,李晓琦,计秉玉,等.中国稠油蒸汽吞吐后提高采收率接替技术前景[J].断块油气田,2022,29(3):378-382,389.FANG Jichao,LI Xiaoqi,JI Bingyu,et al.Prospect of replacement technology for enhanced oil recovery after cyclic steam stimulation of heavy oil in China[J]. Fault-Block Oil&Gas Field,2022,29(3):378-382,389.
- [2]孙江河,范洪富,张付生,等.提高稠油采收率技术概述[J].油田化学,2019,36(2):366-371.SUN Jianghe,FAN Hongfu,ZHANG Fusheng,et al.Overview of improving heavy oil recovery technology[J].Oilfield Chemistry,2019,36(2):366-371.
- [3]卢迎波,胡鹏程,申婷婷,等.电加热辅助蒸汽吞吐提高水平井水平段动用程度的技术[J].大庆石油地质与开发,2022,41(2):167-174.LU Yingbo, HU Pengcheng, SHEN Tingting, et al.Enhancing technique of horizontal section producing degree by electricalheating-assistant steam huff and puff for horizontal well[J].Petroleum Geology&Oilfield Development in Daqing,2022,41(2):167-174.
- [4]张莉.中国石化东部老油田提高采收率技术进展及攻关方向[J].石油与天然气地质,2022,43(3):717-723.ZHANG Li.Progress and research direction of EOR technology in eastern mature oilfields of Sinopec[J]. Oil&Gas Geology,2022,43(3):717-723.
- [5]木合塔尔,高成国,袁士宝,等.红浅1井区注蒸汽后火烧油层生产特征分析[J].大庆石油地质与开发,2021,40(4):73-79.Muhetaer, GAO Chengguo, YUAN Shibao, et al. Analysis on the production characteristics for the in-situ combustion reservoir after steam injection in Well Block HQ1[J].Petroleum Geology&Oilfield Development in Daqing,2021,40(4):73-79.
- [6]曾泉树,汪志明,孙立伟,等.考虑各向异性的蒸汽吞吐效果及见水时间预测[J].断块油气田,2022,29(3):395-398,403.ZENG Quanshu, WANG Zhiming, SUN Liwei, et al. Cyclic steam stimulation effect considering anisotropy and water breakthrough time prediction[J]. Fault-Block Oil&Gas Field,2022,29(3):395-398,403.
- [7]尚策.中深层稠油蒸汽驱开发阶段动态特征[J].特种油气藏,2021,28(5):107-112.SHANG Ce. Dynamic characteristics of development with steam flooding of middle and deep heavy oil[J]. Special Oil&Gas Reservoirs,2021,28(5):107-112.
- [8]李宾飞,臧雨浓,刘小波,等.普通稠油降黏剂辅助氮气吞吐开采机理[J].特种油气藏,2021,28(4):88-95.LI Binfei,ZANG Yunong,LIU Xiaobo,et al.Mechanism of nitrogen stimulation assisted by common heavy oil viscosity reducer[J].Special Oil&Gas Reservoirs,2021,28(4):88-95.
- [9]周林碧,秦冰,李伟,等.国内外稠油降黏开采技术发展与应用[J].油田化学,2020,37(3):557-563.ZHOU Linbi,QIN Bing,LI Wei,et al.Development and application of heavy oil viscosity reduction technology at home and abroad[J].Oilfield Chemistry,2020,37(3):557-563.
- [10]杨森,许关利,刘平,等.稠油化学降粘复合驱提高采收率实验研究[J].油气地质与采收率,2018, 25(5):80-86,109.YANG Sen,XU Guanli,LIU Ping,et al.Experimental study on chemical viscosity-reducing compound flooding for EOR of heavy oil reservoir[J]. Petroleum Geology and Recovery Efficiency,2018,25(5):80-86,109.
- [11]赵长虹,王丽,王攀,等.碳酰胺辅助SAGD提高超稠油Ⅲ类油藏采收率技术[J].特种油气藏,2022,29(4):107-113.ZHAO Changhong,WANG Li,WANG Pan,et al. Carbamideassisted SAGD technology for enhanced oil recovery of classⅢsuper-heavy oil reservoirs[J]. Special Oil&Gas Reservoirs,2022,29(4):107-113.
- [12]朱家杰,毕台飞,马国伟,等.自生热降黏剂的优化及原油降黏解堵性能[J].大庆石油地质与开发,2022,41(2):103-109.ZHU Jiajie,BI Taifei,MA Guowei,et al. Optimization of selfheating viscosity-reducing agent and its performances in oil viscosity reduction and blockage removal[J]. Petroleum Geology&Oilfield Development in Daqing,2022,41(2):103-109.
- [13]王彦玲,许宁,张传保,等.稠油降黏剂的降黏机理研究进展[J].应用化工,2021,50(11):3069-3073.WANG Yanling, XU Ning, ZHANG Chuanbao, et al. Research progress on viscosity reduction mechanism of heavy oil viscosity reducer[J].Applied Chemical Industry,2021,50(11):3069-3073.
- [14]孙永涛,李兆敏,孙玉豹,等.稠油耐高温乳化降黏剂AESO的合成及其性能[J].大庆石油地质与开发,2021,40(3):103-108.SUN Yongtao, LI Zhaomin, SUN Yubao, et al. Synthesis and properties of high-temperature emulsified viscosity reducer AESO for heavy oil[J].Petroleum Geology&Oilfield Development in Daqing,2021,40(3):103-108.
- [15]侯钰,吴运发,秦冰,等.稠油化学降黏技术的研究进展及发展趋势[J].兰州石化职业技术学院学报,2016,16(1):15-19.HOU Yu, WU Yunfa, QIN Bing, et al. The research process and development tendency of viscosity reduction technology in thickened oil chemistry[J]. Journal of Lanzhou Petrochemical College of Vocational Technology,2016,16(1):15-19.
- [16]孟霖,张锁兵,齐义彬,等.高钙镁稠油油藏化学复合驱油体系的研发:以春风油田排601区块为例[J].断块油气田,2022,29(4):556-560.MENG Lin,ZHANG Suobing,QI Yibin,et al. Development of compound chemical flooding system for high calcium and magnesium heavy oil reservoir:Taking Pai 601 Sector of Chunfeng Oilfield as an example[J].Fault-Block Oil&Gas Field,2022,29(4):556-560.
- [17]郭红霞,解玉科,陆建峰,等.稠油改质助剂研究进展[J].特种油气藏,2022,29(6):11-19.GUO Hongxia,XIE Yuke,LU Jianfeng,et al. Review on study of heavy oil modification additives[J].Special Oil&Gas Reservoirs,2022,29(6):11-19.
- [18]李伟忠.胜利油田稠油未动用储量评价及动用对策[J].特种油气藏,2021,28(2):63-71.LI Weizhong. Evaluation and development countermeasures for nonproducing reserves of heavy oil reservoirs in Shengli Oilfield[J].Special Oil&Gas Reservoirs,2021,28(2):63-71.
- [19]韩兴君.硅氧烷季铵盐改性阳离子型两亲聚合物的合成与性能研究[D].济南:山东大学,2018.HAN Xingjun.Study on synthesis and properties of cationic siloxane-modified amphiphilic polymers[D].Jinan:Shandong University,2018.
- [20]费东涛,郭继香,孙建芳,等.一种两亲聚合物稠油降黏剂的制备及性能评价[J].精细化工,2022,39(5):1072-1080.FEI Dongtao, GUO Jixiang, SUN Jianfang, et al.Synthesis and performance evaluation of an amphiphilic polymer viscosity reducer for heavy oil[J].Fine Chemicals,2022,39(5):1072-1080.
- [21]陈明贵,陈登亚,梁洁,等.水溶性两亲聚合物稠油乳化剂的制备及驱油效率[J].油田化学,2019,36(2):306-313.CHEN Minggui, CHEN Dengya, LIANG Jie, et al. New water soluble amphiphilic block copolymer for emulsion flooding of heavy oil[J].Oilfield Chemistry,2019,36(2):306-313.
- [22]郑万刚,束青林,曹嫣镔,等.梳形两亲渗透降黏驱油剂的制备及性能评价[J].油气地质与采收率,2022,29(3):146-152.ZHENG Wangang,SHU Qinglin,CAO Yanbin,et al.Preparation and performance evaluation of comb-shaped amphiphilic permeable agents for viscosity reduction and oil displacement[J].Petroleum Geology and Recovery Efficiency, 2022, 29(3):146-152.
- [23]钱钦,于田田,柏永青,等.两亲性嵌段聚合物稠油降黏剂的合成与性能评价[J].科学技术与工程,2020,20(8):3035-3041.QIAN Qin, YU Tiantian, BAI Yongqing, et al. Synthesis and performance evaluation of amphiphilic block polymer viscosity reducer for heavy oil[J]. Science Technology and Engineering,2020,20(8):3035-3041.
- [24]伍晓妮.两亲性降黏剂合成及性能评价[J].石油地质与工程,2022,36(1):122-126.WU Xiaoni. Synthesis and performance evaluation of amphiphilic viscosity reducer[J]. Petroleum Geology and Engineering,2022,36(1):122-126.
- 稠油油藏
- 乳化降黏剂
- 两亲型聚合物
- 界面活性
- 破乳脱水
heavy oil reservoir - emulsified viscosity reducer
- amphiphilic polymer
- interfacial activity
- demulsification and dehydration