大庆油田化学驱油体系研究现状及发展方向Current research status and development direction of chemical flooding systems in Daqing Oilfield
伍晓林,侯兆伟,王海峰,李勃
WU Xiaolin,HOU Zhaowei,WANG Haifeng,LI Bo
摘要(Abstract):
大庆油田经过多年的研究和实践,创新了聚合物黏弹性理论、表面活性剂与原油匹配关系理论,研制生产出了系列部分水解聚丙烯酰胺、烷基苯磺酸盐、石油磺酸盐,形成第一代化学驱油体系,推进了大庆油田化学驱工业化进程,使化学驱成为油田有效开发主导技术之一。随着大庆油田化学驱开发对象逐渐变差,建立聚合物分子构效关系和稀体系相态转化理论,研究出了系列抗盐聚合物和界面位阻表面活性剂,形成第二代高效化学驱油体系,推动化学驱提质增效。为更大幅度地提高采收率、降低化学剂成本,拓展化学驱应用领域,绿色环保、智能高效、成本低廉的化学驱油体系是今后化学驱油体系发展的主要方向。
For years of research and practice, the theory of polymer viscoelasticity and the theory of matching relationship between surfactant and crude oil are innovated in Daqing Oilfield. A series of partially hydrolyzed polyacrylamide, alkylbenzene sulfonate and petroleum sulfonate are developed and produced, forming the first generation of chemical flooding systems, which promotes commercialization process of chemical flooding and makes chemical flooding become one of dominant technologies for effective development in Daqing Oilfield. As development targets of chemical flooding in Daqing Oilfield gradually deteriorate, polymer molecular structure-activity relationship and dilute system phase transition theory are developed. A series of salt-resistant polymers and interfacial steric hindrance surfactants are studied, forming the second generation of efficient chemical flooding system and promoting quality and efficiency improvement of chemical flooding. In order to further improve oil recovery significantly, reduce chemical agent costs and expand application areas, the main direction for future development of chemical flooding systems is proposed as environmental friendly, intelligent and efficient, and low-cost.
关键词(KeyWords):
化学驱;聚合物;复合体系;研究现状;发展方向;大庆油田
chemical flooding;polymer;combination flooding system;research status;development direction;Daqing Oilfield
基金项目(Foundation): 中国石油天然气股份有限公司攻关应用性专项“中高渗油田特高含水期大幅度提高采收率技术研究”(2023ZZ22)
作者(Author):
伍晓林,侯兆伟,王海峰,李勃
WU Xiaolin,HOU Zhaowei,WANG Haifeng,LI Bo
DOI: 10.19597/J.ISSN.1000-3754.202403016
参考文献(References):
- [1]王德民.技术创新大幅度增加大庆油田可采储量确保油田长期高产[J].大庆石油地质与开发,2019,38(5):8-17.WANG Demin. Technical innovation greatly increase the recoverable reserve and ensure long-term high production of Daqing Oilfield[J]. Petroleum Geology&Oilfield Development in Daqing,2019,38(5):8-17.
- [2]袁庆峰,朱丽莉,陆会民,等.水驱油田晚期开发特征及提高采收率主攻方向[J].大庆石油地质与开发,2019,38(5):34-40.YUAN Qingfeng, ZHU Lili, LU Huimin, et al. Development characteristics and main tackled EOR research direction for the water flooded oil field at the late stage[J]. Petroleum Geology&Oilfield Development in Daqing,2019,38(5):34-40.
- [3]王凤兰,沙宗伦,罗庆,等.大庆油田特高含水期开发技术的进步与展望[J].大庆石油地质与开发,2019,38(5):51-58.WANG Fenglan,SHA Zonglun,LUO Qing,et al. Progress and prospects of the developing techniques in ultra-high water-cut period of Daqing Oilfield[J]. Petroleum Geology&Oilfield Development in Daqing,2019,38(5):51-58.
- [4]王德民,程杰成,杨清彦.黏弹性聚合物溶液能够提高岩心的微观驱油效率[J].石油学报,2000,21(5):45-51.WANG Demin, CHENG Jiecheng, YANG Qingyan. Viscouselastics polymer can Increase micro-scale displacement efficiency in cores[J]. Acta Petrolei Sinica,2000,21(5):45-51.
- [5]王德民,王刚,吴文祥,等.黏弹性驱替液所产生的微观驱力对驱油效率的影响[J].西安石油大学学报(自然科学版),2008,23(1):43-55.WANG Demin,WANG Gang,WU Wenxiang,et al. Influence of the micro-force produced by viscoelastic displacement liquid on displacement efficiency[J]. Journal of Xi’an Shiyou University(Natural Science Edition),2008,23(1):43-55.
- [6]伍晓林,楚艳苹.大庆原油中酸性及含氮组分对界面张力的影响[J].石油学报(石油加工),2013,29(4):681-686.WU Xiaolin,CHU Yanping. Effect of acid and nitrogen containing heterocyclic compounds on water-oil interfacial tension of Daqing crude oil[J]. Acta Petrolei Sinica(Petroleum Processing Section),2013,29(4):681-686.
- [7]孙龙德,伍晓林,周万富,等.大庆油田化学驱提高采收率技术[J].石油勘探与开发,2018,45(4):636-645.SUN Longde,WU Xiaolin,ZHOU Wanfu,et al. Technologies of enhancing oil recovery by chemical flooding in Daqing Oilfield[J]. Petroleum Exploration and Development,2018,45(4):636-645.
- [8]高树堂.大庆馏分油石油磺酸盐的合成和分析[J].油田化学,1989,6(1):65-71.GAO Shutang. Synthesis and analysis of petroleum sulfonates from fractions of Daqing crude oil[J]. Oilfield Chemistry,1989,6(1):65-71.
- [9]伍晓林,张国印,刘庆梅,等.石油羧酸盐的研制及其在三次采油中的应用[J].油气地质与采收率,2001, 8(1):62-63.WU Xiaolin, ZHANG Guoyin, LIU Qingmei, et al. Development of petroleum carboxylate and its application in tertiary recovery[J]. Petroleum Geology and Recovery Efficiency,2001,8(1):62-63.
- [10]赵颖华,徐艳姝,王海峰,等.木质素磺酸盐的改性及其在三次采油中的应用[J].大庆石油地质与开发,2005,24(4):90-91.ZHAO Yinghua,XU Yanshu,WANG Haifeng,et al. Modification and application of lignosulfonate for enhanced oil recovery[J]. Petroleum Geology&Oilfield Development in Daqing,2005,24(4):90-91.
- [11]张国印,伍晓林,廖广志,等.三次采油用烷基苯磺酸盐类表面活性剂研究[J].大庆石油地质与开发,2001,20(2):26-27.ZHANG Guoyin,WU Xiaolin,LIAO Guangzhi, et al.Study on the surfactant of alkyl benzene sulfonate used for tertiary recovery[J]. Petroleum Geology&Oilfield Development in Daqing,2001,20(2):26-27.
- [12]伍晓林,侯兆伟,杨勇,等.古龙1号乳液体系研制及性能评价[J].大庆石油地质与开发,2022,41(3):112-119.WU Xiaolin,HOU Zhaowei,YANG Yong,et al. Development and performance evaluation for Gulong 1#emulsion system[J].Petroleum Geology&Oilfield Development in Daqing,2022,41(3):112-119.
- [13] LI C C,LI Y H,PU H. Molecular simulation study of interfacial tension reduction and oil detachment in nanochannels by surfacemodified silica nanoparticles[J]. Fuel,2021,292:120318.
- [14]王志华,许云飞,戚向东,等.乳状液稳定性影响因素及其分子动力学模拟研究进展[J].油田化学,2021,38(2):360-367.WANG Zhihua, XU Yunfei, QI Xiangdong, et al. Research progress on influencing factors of emulsion stability with molecular dynamics simulation[J]. Oilfield Chemistry,2021,38(2):360-367.
- [15] SONG S H, ZHANG H, SUN L, et, al. Molecular dynamics study on aggregating behavior of asphaltene and resin in emulsion heavy oil droplets with sodium dodecyl sulfate[J]. Energy&Fuels,2018,32(12):12383-12393.
- [16] RUHLAND T M, GR?SCHEL A H, WALTHER A, et al.Janus cylinders at liquid-liquid interfaces[J]. Langmuir,2011,27(16):9807-98021.