海上砂岩油藏注自生CO2体系实验及提高采收率机理In-situ CO2 generation system injection experiment and EOR mechanism for offshore sandstone reservoirs
郑玉飞,李翔,刘文辉,冯轩,宫汝祥,王硕
ZHENG Yufei,LI Xiang,LIU Wenhui,FENG Xuan,GONG Ruxiang,WANG Shuo
摘要(Abstract):
针对自生CO_2技术增产功能多元化、提高采收率机理认识不清的问题,综合利用理化性能评价、岩心驱替及结构表征实验,通过研究体系配方、界面张力、原油黏度、提高采收率效果及岩心孔喉结构的变化,明确了自生CO_2技术的主要增产机理。实验结果表明:自生CO_2体系中最佳的生气剂与释气剂物质的量浓度比为1∶2,最佳体系质量分数为21.5%,此时的CO_2生气效率接近最大值。自生CO_2体系在均质和非均质岩心中均具有良好的驱替效率,注入自生CO_2体系提高原油采收率(EOR)的机理主要包括:(1)体系中的生气剂(碱性)可以降低原油与体系间的界面张力(IFT);(2)在地层中产生的CO_2会使原油膨胀、降低原油黏度;(3)生气剂与释气剂反应放热可溶解有机物并提高采收率,CO_2生成过程和清除堵塞引起的压力波动也有助于改变驱油路径、提高采收率。研究成果为自生CO_2的技术优化和矿场实践提供了依据。
Facing the problem of unclear mechanism of enhanced oil recovery due to diversified stimulation functions of in-situ CO_2 generation technology, the main stimulation mechanisms are determined comprehensively by physicochemical properties evaluation, core displacement and structural characterization experiments, and by study on system formula, interfacial tension, oil viscosity, enhanced recovery effect and changes of core pore throats structure. The results show that the optimum amount-of-substance concentration ratio of gas-generating agent to gas-releasing agent is 1∶2 and the optimum system mass fraction is 21.5%, with gas generation efficiency close to the maximum value. In-situ CO_2 generation system has high displacement efficiency in both homogeneous and heterogeneous cores. The EOR mechanism of in-situ CO_2 generation system injection mainly includes:(1)gas-generating agent(alkaline) reduces the interfacial tension between oil and system(IFT);(2)the CO_2 produced in the formation expands the oil and reduces oil viscosity;(3)the heat released by reaction of gas-generating agent and gas-releasing agent dissolves organic matter and increases recovery.The pressure fluctuations in the process of CO_2 generation and clogs removing also help changing the displacement path. The research results provide basis for optimization and field application of in-situ CO_2 generation technology.
关键词(KeyWords):
自生CO_2;EOR;海上油田;机理研究
in-situ CO_2 generation;EOR;offshore oilfield;mechanism study
基金项目(Foundation): 中海油田服务股份有限公司科技项目“‘N+1’轮层内生成CO2调驱效果优化研究与应用”(YSB19YF019);中海油田服务股份有限公司科技项目“海上陆相砂岩油藏均衡驱油技术研究与应用”(YSB20YF001)
作者(Author):
郑玉飞,李翔,刘文辉,冯轩,宫汝祥,王硕
ZHENG Yufei,LI Xiang,LIU Wenhui,FENG Xuan,GONG Ruxiang,WANG Shuo
DOI: 10.19597/j.issn.1000-3754.202203059
参考文献(References):
- [1]李阳.低渗透油藏CO2驱提高采收率技术进展及展望[J].油气地质与采收率,2020,27(1):1-10.LI Yang. Technical advancement and prospect for CO2 flooding enhanced oil recovery in low permeability reservoirs[J].Petroleum Geology and Recovery Efficiency,2020,27(1):1-10.
- [2]贾连超,刘鹏飞,袁丹,等.注CO2提高页岩吸附气采收率实验:以鄂尔多斯盆地延长组长7页岩气为例[J].大庆石油地质与开发,2021,40(2):153-159.JIA Lianchao, LIU Pengfei, YUAN Dan, et al. Experiment of enhancing the recovery of the shale adsorbed gas by CO2 injection:Taking Yanchang-Formation Chang-7 shale gas in Ordos Basin as an example[J]. Petroleum Geology&Oilfield Development in Daqing,2021,40(2):153-159.
- [3]邓宏伟.超深层低渗透稠油CO2增溶降黏体系研发与应用[J].油气地质与采收率,2020,27(1):81-88.DENG Hongwei. Development and application of CO2 solubilizing and viscosity reducing system for ultra-deep and low-permeability heavy oil reservoirs[J]. Petroleum Geology and Recovery Efficiency,2020,27(1):81-88.
- [4]曹小朋,冯其红,杨勇,等. CO2-原油混相带运移规律及其对开发效果的影响[J].油气地质与采收率,2021,28(1):137-143.CAO Xiaopeng, FENG Qihong, YANG Yong, et al. Migration law of CO2-crude oil miscible zone and its influence on development effect[J]. Petroleum Geology and Recovery Efficiency,2021,28(1):137-143.
- [5]陈兴隆,韩海水,李实,等.CO2启动盲端孔隙残余油的微观特征[J].油气地质与采收率,2020,27(1):50-56.CHEN Xinglong, HAN Haishui, LI Shi, et al. Microscopic characteristics of residual oil in dead-end pores initiated by CO2[J]. Petroleum Geology and Recovery Efficiency, 2020, 27(1):50-56.
- [6]赵凤兰,宋黎光,冯海如,等.厚层砂岩油藏原油密度影响下的CO2驱重力超覆实验[J].断块油气田,2021,28(6):842-847.ZHAO Fenglan, SONG Liguang, FENG Hairu, et al. Experimental study of CO2 gravity segregation effected by oil density in thick sandstone reservoirs[J]. Fault-Block Oil&Gas Field,2021,28(6):842-847.
- [7]赖南君,郝丹,朱元强,等.低渗透油藏CO2驱封窜用CO2/N2响应性纳米分散体系的研制[J].油气地质与采收率,2022,29(2):77-84.LAI Nanjun,HAO Dan,ZHU Yuanqiang,et al.Development of CO2/N2 responsive nano-dispersion system for channeling blocking during CO2 flooding in low-permeability reservoirs[J]. Petroleum Geology and Recovery Efficiency,2022,29(2):77-84.
- [8]周拓,刘学伟,杨正明,等.二氧化碳驱储集层堵塞机理实验分析[J].石油勘探与开发,2015,42(4):502-506.ZHOU Tuo,LIU Xuewei,YANG Zhengming,et al. Experimental analysis on reservoir blockage mechanism for CO2 flooding[J].Petroleum Exploration and Development, 2015, 42(4):502-506.
- [9]吴俊峰,刘宝忠,刘道杰,等.二氧化碳混相压裂吞吐实验[J].特种油气藏,2022,29(5):126-131.WU Junfeng,LIU Baozhong,LIU Daojie,et al.Test of CO2 Miscible Fracturing and Huff and Puff[J].Special Oil&Gas Reservoirs,2022,29(5):126-131.
- [10]苗万春,何善斌,张兴,等.致密砂岩油藏CO2驱替沥青质沉积及储层伤害特征[J].成都理工大学学报(自然科学版),2021,48(5):573-581.MIAO Wanchun,HE Shanbin,ZHANG Xing,et al.Characteristics of asphaltene deposition and reservoir damage caused by CO2flooding in tight sandstone reservoir[J].Journal of Chengdu University of Technology(Science&Technology Edition),2021,48(5):573-581.
- [11]侯智玮,刘勇,叶锋,等.基于GPR-DE模型的CO2-原油体系最小混相压力研究[J].油气地质与采收率,2021,28(3):126-132.HOU Zhiwei, LIU Yong, YE Feng, et al. Study on minimum miscibility pressure of CO2-crude oil system based on GPR-DE model[J].Petroleum Geology and Recovery Efficiency,2021,28(3):126-132.
- [12]金发扬,周顺明,高士博,等.层内自生CO2提高采收率技术现状[J].油田化学,2021,38(3):564-570.JIN Fayang, ZHOU Shunming, GAO Shibo, et al. Status of enhanced oil recovery technology by in-situ CO2 generated in the formation[J].Oilfield Chemistry,2021,38(3):564-570.
- [13]郑玉飞,李翔,徐景亮,等.层内自生CO2提高采收率技术在海上油田的研究及应用[J].石油与天然气化工,2019,48(6):70-74.ZHENG Yufei, LI Xiang, XU Jingliang, et al. Research and application of EOR technology by in-situ CO2 generation on offshore oilfield[J].Chemical Engineering of Oil and Gas,2019,48(6):70-74.
- [14] GUMERSKY K K,DZHAFAROV I S,SHAKHVERDIEV A K,et al. In-situ generation of carbon dioxide:New way to increase oil recovery[R].SPE 65170,2000.
- [15] SHIAU B J B,HSU T P,ROBERTS B L,et al.Improved chemical flood efficiency by in situ CO2 generation[R]. SPE 129893,2010.
- [16]张国萍,肖良,胡艳霞,等.层内生气提高采收率技术在中原断块油田的应用[J].油气地质与采收率,2004,11(5):60-61.ZHANG Guoping,XIAO Liang,HU Yanxia,et al.Applications of in situ gas generating for enhanced oil recovery to Zhongyuan faulted block oilfield[J].Petroleum Geology and Recovery Efficiency,2004,11(5):60-61.
- [17] JIN F Y,LIU Z Z,PU W F,et al.Experimental study of in-situ CO2foam technique and application in Yangsanmu Oilfield[J].Journal of Surfactants and Detergents,2016,1(6):1231-1240.
- [18]杨付林,朱伟民,余晓玲,等.层内生气吞吐工艺在江苏油田W5稠油油藏的应用[J].复杂油气藏,2013,6(3):71-75.YANG Fulin,ZHU Weimin,YU Xiaoling,et al.Application of in-situ generation gas huff-n-puff process in W5 heavy oil reservoir of Jiangsu Oilfield[J]. Complex Hydrocarbon Reservoirs,2013,6(3):71-75.
- [19]郑玉飞,李翔,徐景亮,等.渤海P油田层内生成CO2调驱技术[J].石油钻探技术,2020,48(2):108-112.ZHENG Yufei,LI Xiang,XU Jingliang,et al.In-Situ CO2 generation technology in Bohai P Oilfield[J].Petroleum Drilling Techniques,2020,48(2):108-112.
- [20]郑玉飞,李翔,徐景亮,等.储层非均质性对自生CO2调驱效果的影响[J].岩性油气藏,2020,32(2):122-128.ZHENG Yufei,LI Xiang,XU Jingliang,et al.Influence of vertical heterogeneity of reservoirs on in-situ CO2 profile control and flooding effects[J]. Lithologic Reservoirs, 2020, 32(2):122-128.
- [21]周锋,高伟,李晓明,等.二维多孔介质CO2混相驱油质量浓度分布[J].断块油气田,2021,28(1):120-123,128.ZHOU Feng,GAO Wei,LI Xiaoming,et al.Mass concentration distribution of CO2 miscible flooding in 2-D porous media[J].Fault-Block Oil&Gas Field,2021,28(1):120-123,128.
- [22]李晓枫,彭勃,刘琦,等.微泡沫驱提高采收率技术研究进展[J].油气地质与采收率,2022,29(4):91-100.LI Xiaofeng,PENG Bo,LIU Qi,et al.Research progress of micro-foam flooding technology for enhanced oil recovery[J].Petroleum Geology and Recovery Efficiency,2022,29(4):91-100.
- [23]孙大龙,张广东,彭旭,等.CO2驱气溶性降混剂提高采收率机理实验[J].特种油气藏,2022,29(1):134-140.SUN Dalong,ZHANG Guangdong,PENG Xu,et al.Experiment on the mechanism of enhancing oil recovery by CO2 flooding with gas-soluble demixing agent[J]. Special Oil&Gas Reservoirs,2022,29(1):134-140.
- [24]张怿赫,盛家平,李情霞,等.CO2吞吐技术应用进展[J].特种油气藏,2021,28(6):1-10.ZHANG Yihe,SHENG Jiaping,LI Qingxia,et al.Advances in the application of CO2 stimulation technology[J].Special Oil&Gas Reservoirs,2021,28(6):1-10.
- [25] COSKUN O,GRIGG R,SVEC R,et al.The effect of salinity on in-situ generated CO2 gas:Simulations and experiments[C].Chicago:American Society of Mechanical Engineers International Mechanical Engineering Congress and Exposition 2006,2006.
- [26]油气计量及分析方法专业标准化技术委员会.原油黏度测定旋转黏度计平衡法:SY/T 0520—2008[S].北京:国家发展和改革委员会,2008.Standardization Technical Committee of Petroleum and Gas Measurement and Analysis Methods.Viscosity determination of crude petroleum-Equilibrium method by rotational viscometer:SY/T 0520—2008[S].Beijing:National Development and Reform Commission,2008.