煤层气泡沫压裂低表面张力起泡剂实验EXPERIMENT OF THE LOW-SURFACE-TENSION FOAMING AGENT APPLIED IN CBM FOAM FRACTURING
丁昊明,戴彩丽,由庆,赵明伟,管保山,刘萍
DING Haoming,DAI Caili,YOU Qing,ZHAO Mingwei,GUAN Baoshan,LIU Ping
摘要(Abstract):
针对煤层气泡沫压裂液表面张力高,压裂液滞留煤层造成地层伤害的问题,研制了低表面张力氟碳表面活性剂(AS-3)。实验测定AS-3溶液的表面张力、吸附量、泡沫综合值和悬浮性能,结果表明:质量分数0.3%的AS-3溶液表面张力为16.23 mN/m;在煤表面达到吸附平衡时,饱和吸附量为17.70 mg/g;AS-3水溶液对粒径超过100目的煤粉具有良好悬浮能力。AS-3溶液性能良好,配液简单,适用于煤层气等非常规储层的压裂。
In the light of the problems of the high surface tension,entrapment in the coal beds and damage caused from the above remains,the fluorocarbon anionic surfactant with low surface tension(AS-3) is developed.The surface tension,adsorbed capacity,comprehensive value of the foam and suspending performance of the surfactant solution are tested.The results show that the tension of the solution with 0.3%mass fraction is 16.23 mN/m;when the adsorption on the surface of the coal reaches the state of equilibrium,the saturated adsorption capacity is 17.70mg/g;for the braize with a particle diameter of more than 100 meshes,AS-3 water solution possesses much better suspending performance.AS-3 water solution is characterized by favorite capacity and simple to prepare the solution and moreover adaptive to the fracturing of those unconventional reservoirs with CBM and so on.
关键词(KeyWords):
起泡剂;泡沫综合值;煤层气;泡沫压裂液;表面张力;吸附量
foaming agent;comprehensive value of the foam;coal bed methane(CBM);foam fracturing fluid;surface tension;adsorbed capacity
基金项目(Foundation): “十二五”国家科技重大专项“大型油气田及煤层气开发专项氮气泡沫压裂液起泡剂研发”(2011ZX05037003-001);; 教育部2012年度高等学校博士学科点专项科研基金资助课题“煤层气泡沫压裂液用高效起泡剂的合成及在煤表面聚集行为研究”(20120133110010)
作者(Author):
丁昊明,戴彩丽,由庆,赵明伟,管保山,刘萍
DING Haoming,DAI Caili,YOU Qing,ZHAO Mingwei,GUAN Baoshan,LIU Ping
参考文献(References):
- [1]陈江,吕建伟,郭东鑫,等.煤层气产能影响因素及开发技术研究[J].资源与产业,2011,13(1):108-110.
- [2]张林,刘池阳,李志航,等.煤层气井水力压裂合适伴注气体的选择[J].煤炭学报,2008,33(3):322-324.
- [3]刘宏生,于涛,曹瑞波,等.超低界面张力泡沫体系抗油砂吸附性能[J].大庆石油地质与开发,2012,31(4):139-143.
- [4]徐江伟.消泡剂的复合及其消泡机理探讨[J].中国甜菜糖业,2002,4(11):31-33.
- [5]赖崇伟.新型抗油、抗盐起泡剂体系的研究[D].成都:四川大学,2007.
- [6]王萌萌,郭红东.泡沫剂的发泡性能及其影响因素[J].精细石油化工进展,2007,12(8):40-42.
- [7]盛强,郭平,陈静,等.多孔介质中泡沫的直观特征研究[J].特种油气藏,2012,19(4):126-129.
- [8]马健,张春龙.CO_2压裂技术在杏南试验区的应用研究[J].大庆石油地质与开发,2008,27(3):98-101.
- [9]王丽伟,管保山,梁利.煤粉悬浮剂的作用机理及性能[J].中国煤层气,2011,8(1):23-25.
- [10]Crawford R J,Mainwaring D E.The influence of surfactant adsorption on the surface characterization of Australian coals[Jj.Fuel,2001,80(4):313-320.
- [11]牟善波,张士诚,张劲,等.新型阴离子表活剂压裂液性能评价及现场应用[J].大庆石油地质与开发,2010,29(1):81-84.
- [12]杨筱璧.泡沫排水起泡剂室内实验优选[J].特种油气藏,2009,16(2):70-75.
- 起泡剂
- 泡沫综合值
- 煤层气
- 泡沫压裂液
- 表面张力
- 吸附量
foaming agent - comprehensive value of the foam
- coal bed methane(CBM)
- foam fracturing fluid
- surface tension
- adsorbed capacity